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Adhesion Promoters

3-Mercaptopropyltrimethoxysilane | Manta S31

Manta S31 is 3-mercaptopropyltrimethoxysilane (CAS 4420-74-0), a sulfur-functional coupling agent and adhesion promoter used in silica-reinforced tire treads, polysulfide and polyurethane sealants, metal primers and copper foil treatment. Its mercapto group provides strong adhesion to copper, silver, gold, aluminum and stainless steel, and it releases methanol on hydrolysis.

Grade
S31
Chemical Name
3-Mercaptopropyltrimethoxysilane
CAS No.
4420-74-0
EINECS
224-588-5
Formula
C6H16O3SSi
Form
Colorless Transparent Liquid

Overview

Manta S31 is a bifunctional organosilane with a reactive mercapto (-SH) group and three hydrolyzable methoxysilyl groups. Its sulfur-based chemistry lets it act as a coupling agent between sulfur-vulcanized rubbers or reactive resins and inorganic fillers or substrates.

In silica-reinforced tire treads, S31 chemically bonds silica to SBR and BR polymers, reducing rolling resistance while improving wet grip and tread wear resistance. The mercapto group can also participate in radical polymerization or react with isocyanates and epoxies, and S31 improves the moisture and corrosion resistance of sealants and coatings.

S31 differs from amino-functional grades such as Manta A111 and epoxy-functional grades such as Manta E560 in its functional group. The mercapto group is the reason for its use with non-ferrous metals and in rubber compounds that couple silica to organic polymers.

Key Features

  • Strong adhesion to copper, silver, gold, aluminum and stainless steel
  • Couples silica to SBR and BR polymers for lower rolling resistance and better wet grip
  • Mercapto group participates in radical polymerization or reacts with isocyanates and epoxies
  • Improves moisture and corrosion resistance of sealants and coatings
  • Releases methanol on hydrolysis

Cross-Reference

Manta S31 can be considered as an alternative to Momentive Silquest A-189, Evonik Dynasylan MTMO and Shin-Etsu KBM-803.

Trademarks are the property of their respective owners; no affiliation is implied.

Specifications

Typical properties of Manta S31
PropertyTypical Value
Molecular Weight196.34
AppearanceColorless Transparent Liquid
Colour (Pt-Co)30 max
Density (ρ20°C, g/cm³)1.0570±0.0050
Refractive Index (n25/D)1.4300–1.4500
Purity (by GC, %)98.0 min

Typical values from the current Technical Data Sheet.

Applications

  • Rubber: silica-reinforced tire tread compounds and mineral-reinforced goods such as shoe soles, industrial rollers and mechanical rubber parts
  • Polysulfide and polyurethane sealants: internal adhesion promoter for water-resistant bonding to glass and metals, including insulating glass sealants, automotive windshield adhesives and architectural joint sealants
  • Protective coatings and metal primers: additive or primer improving the adhesion of epoxy and polyurethane coatings to copper, silver, gold, aluminum and stainless steel, helping to limit sub-film corrosion and substrate oxidation
  • Electronics and copper foil: surface treatment of copper foils and silver-based conductive inks for peel strength and reliability in flexible printed circuits and laminates
  • Resin modification and composites: chemical modification of butyl, neoprene, nitrile, SBR, epoxy, phenolic and polyurethane systems, and coupling agent in silica-, talc- or mica-filled composites
  • Foundry and abrasives: additive to phenolic and furan resins for sand core strength and moisture resistance, and strengthens the bond between abrasive grains and resin binder
  • Precision metal surfaces: thin-film surface modifier providing a hydrophobic, anti-corrosive layer that facilitates subsequent bonding

Related applications: Adhesives & Sealants · Paints & Coatings · Composites & Fiberglass · Rubber & Tires

Packaging & Storage

Supplied in 20 kg pail, 190 kg drum, 200 kg drum.

Safety and Storage

Keep away from heat and open flame. When stored at or below 25°C in the original unopened containers, Shelf life is 24 months.

Documents

Frequently Asked Questions

How does Manta S31 improve green tire compounds?

In silica-reinforced tire treads, S31 chemically bonds inorganic silica to organic polymers such as SBR and BR. This reduces rolling resistance while improving wet grip and tread wear resistance.

Which metals does Manta S31 improve adhesion to?

The mercapto (-SH) group has a high affinity for non-ferrous metals. In epoxy or polyurethane coatings and primers, S31 improves adhesion to copper, silver, gold, aluminum and stainless steel and helps to limit sub-film corrosion and oxidation of the substrate.

What is the function of Manta S31 in polysulfide and polyurethane sealants?

It acts as an internal adhesion promoter in one- and two-part polysulfide and polyurethane sealants, giving water-resistant bonding to glass and metal surfaces. Typical uses include insulating glass (IG) sealants, automotive windshield adhesives and architectural joint sealants.

Can Manta S31 be used in foundry resins and abrasives?

Yes. It is added to phenolic and furan resins to improve the strength and moisture resistance of foundry sand cores. In resin-bonded abrasives it strengthens the bond between abrasive grains, such as silicon carbide or alumina, and the resin binder, leading to longer tool life.

Can I request a sample and documents for Manta S31?

Yes. Samples are charged. The sample fee includes courier delivery and is deducted from your first formal order. Use Request a Sample and include the quantity and your application. The TDS is on this page; SDS and COA are available on request.

Looking for a different purity, functional group, or a structure not listed here? Contact our technical team.

Talk to our technical team

Tell us your application, target properties and estimated quantity. We will suggest grades and arrange documents or samples.